WebIn this account, we summarize recent work on the direct introduction of the SCF3 group by using [ (bpy)CuSCF3] as trifluoromethylthiolating reagent. A number of efficient and … WebApr 15, 2016 · Proposed Mechanism for the Enantioselective Alkynylation of an Aryl Trifluoromethyl Ketone, the Key Step in the Synthesis of Efavirenz. Gareth J. Griffiths. and. Aleksander Warm *. Organic Process …
Cu-mediated oxidative trifluoromethylthiolation of arylboronic …
WebA practical and reproducible procedure for the efficient preparation of (bpy)CuSCF3 1, a copper reagent for trifluoromethylthiolation reaction, is reported. All reaction parameters were optimized ... WebAn efficient protocol for the copper-mediated trifluoromethylthiolation of heteroaryl bromides has been achieved using the copper complex (bpy)Cu(SCF3) as trifluoromethylthiolating reagent. This procedure provides a straightforward synthetic method for heteroaryl trifluoromethyl sulfides from readily available, simple starting materials. just princesses book 2
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WebIn this account, we summarize recent work on the direct introduction of the SCF3 group by using [(bpy)CuSCF3] as trifluoromethylthiolating reagent. A number of efficient and convenient strategies ... WebJul 2, 2014 · A range of functional groups, including ethers, thioether, esters, nitriles, amides, and ketal groups, were well tolerated in the electrophilic partner and variation of the solvent, additives and time allowed optimization of the reaction. A general and convenient copper-mediated trifluoromethylthiolation of primary and secondary alkyl halides was … WebAn operationally simple method for the copper-mediated trifluoromethylthiolation of iodopyridinones employing (bpy)CuSCF3 (1; bpy = 2,2'-bipyridine) as a trifluoromethylthiolating reagent is … Expand. 12. PDF. Save. Alert. Synthesis of Vinyl Trifluoromethyl Thioethers via Copper-Mediated Trifluoromethylthiolation of Vinyl Bromides. laurel river lake crappie fishing